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Ask Wine Wizard

High-pH Wine

TroubleShooting

Hunter Nolen — New Braunfels, Texas asks,
Q

Thanks again for your help in saving my high-sugar Viognier a couple of years ago. It is all gone now! I grow Syrah, Tempranillo, and Mourvèdre. In the Texas Hill Country the grapes “cry uncle” around the third week of July and I have to harvest or they will abruptly collapse in the relentless 100 °F (38 °C)+ heat. Because of the abruptness of collapse, I have learned to pick early rather than late because early means usable grapes and late means mush! I therefore end up picking on the third weekend in July when I can generally count on little rot, decent maturity, and available family and friends to help.

Also, due to the daytime heat and little relief through the night, I generally wind up with high pH. This year my pH came in at what I consider quite acidic for my vineyard (3.4), while my sugar was light (about 21 °Brix). I therefore chaptalized to about 24 °Brix before pitching my yeast. After fermentation, my pH had risen to right around 3.7, and I get a little nervous about long-term stability above 3.65. My inclination has always been to acidulate to around 3.65, which makes me more comfortable and usually does not tarten up the wine too terribly much.

I am generally inclined to conduct MLF on my red wine even though the pH is on the high side. I like to know my wine is stable for the long run, and generally favor the idea of converting my malic acid to lactic acid for flavor and mouthfeel reasons. But, I have seen some literature that suggests foregoing MLF on high-pH wines. This year I have done no acidulation yet and started my MLF culture going on the pH 3.7 wine. Finally, after MLF this year I fully expect my pH to be up around 3.8.

OK, enough of the chatter. My questions below in orange

A

Q
In the above situation, what do you suggest I do? Do you agree that I should conduct MLF on my wines considering their high-pH characteristics?

A
First off, glad your Viognier got better! That’s awesome you’re doing both reds and whites, it’s fun to try a lot of different kinds of wines. Well, I hear you about heat — I grow some grapes in Paso Robles region of California and we definitely have high pH problems as it gets so hot. For your Texan reds, even though the pH is creeping up at 3.7 post-primary fermentation, I still encourage MLF in this situation because aging red wines are always a risk for in-barrel or in-bottle MLF, both of which can cause off aromas and flavors and can ruin your wine.

Q
What is your absolute top-end pH that you personally will not go above in a finished red wine?

Keeping a close eye on pH using a properly calibrated pH meter can be critical for longer-term storage when acidity levels are in question.

A
I don’t like to go above 3.85 at bottling, though that means you need to really have great sanitation, no headspace, and minimize oxygen exposure. It’s also not a safe pH to be storing wine in barrels for two years. You could do what some high-end Napa Valley producers do — store their wine for long term aging at 3.55–3.6 pH, then add carbonate about a month before bottling to adjust pH up to around 3.8-ish. If you sterile filter and bottle with free SO2 of around 28 ppm or so, you’ll have little chance of anything cropping up in the bottle.

Q
And, if you end up with a wine around pH 3.8 that tastes good as-is, what do you consider to be top-end [sulfite]? Sulfite efficacy charts I refer to from winemakermag.com/sulfitecalculator indicates I need around 100 mg/L FSO2 in order to be protective but that has its downside on aroma, flavor, and color. These are my WWAD questions (What would Alison do)?

A
Hahaha, you’re funny. Again, you could store at a lower pH so you wouldn’t have to use so much SO2 over the wine’s lifetime, then raise the pH right before bottling. Storing long-term at 3.8 pH really isn’t safe and I would definitely go down to a 3.6–3.65. A pH 3.8 for bottling, as I mention above, isn’t unusual for big reds — and then I wouldn’t bottle with more than 30 ppm FSO2. I know it’s not correct from a molecular SO2 level, but seriously, it’s really difficult to achieve the holy grail of 0.8 molecular SO2, (or 0.5 recommended for red wines) as the charts would have you try for and not have your wine’s flavor and aroma suffer. So I (and most other commercial winemakers I know) would never even try for this level. We angle for that delicate balance between antioxidant and microbial protection for our wines and overall quality. This is why great sanitation, as well as having a handle on what kinds of microbes live in your cellar and wines while aging, can be really important information to have. It’s also why filtering finished wines before bottling isn’t a bad idea. If you filter your wine it’ll allow you to have slightly lower molecular SO2 levels over a wine’s lifetime but especially right before bottling.

Response by Alison Crowe.